Konten Lembar Data
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 25.01.2011
Revision 19.01.2011
R-134a (1,1,1,2,-Tetrafluorethan) type test leak (n.
r.)
1. Identification of the substance/mixture and of the company/undertaking
Product identifier
Name of product R-134a (1,1,1,2,-Tetrafluorethan) type test leak (n.r.)
Name of substance 1,1,1,2-Tetrafluoroethane (R-134a); Norflurane
EC No 212-377-0
CAS No 811-97-2
Distributor CBM
3 Rue Jules Verne
Parc d'Activités Airspace
33185 Le Haillan
Advice
Emergency advice
Recommended intended purpose(s)
test gas
2. Hazards identification
Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]
Hazard classes and Hazard Hazard Statements Classification procedure
categories
Liquef. Gas H280
Hazard Statements
'--" H280 Contains gas under pressure; may explode if heated.
Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]
GHS04
Signal word
Warning
Hazard Statements
H280 Contains gas under pressure; may explode if heated.
Precautionary Statements
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
Hazardous ingredients for labeling
1,1,1,2-Tetrafluoroethane (R-134a); Norflurane
Page 1/6
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 25.01.2011
Revision 19.01.2011 -.._./
R-134a (1,1,1,2,-Tetrafluorethan) type test leak (n.
r.)
Information pertaining to special dangers for human and environment
No hazardous product as specified in Directive 67/548/EEC.
Rapid evaporation of the liquid can cause cold burns.
Vapours are heavier than air and may cause asphyxiation due to oxygen displacement from the atmosphere.
Container under pressure. Protect from direct sunlight and temperatures above 50 ° C. Do not spray into flames or onto
glowing abjects.
3. Composition/information on ingredients
Description
pressure-liquefied gas
CAS No 811-97-2 1, 1, 1,2-Tetrafluoroethane (R-134a); Norflurane
EC No 212-377-0
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
ln case of inhalation
Remove the casualty into fresh air and keep him immobile.
ln high concentrations may cause asphyxiation.
Remove aggrieved persans from danger zone
ln the event of symptoms refer for medical treatment.
ln case of respiratory standstill give artifical respiration by respirator and send for a doctor.
ln case of skin contact
ln case of contact with skin wash off with water.
ln case of frostbite rinse with plenty of water. Don't remove clothing.
ln case of eye contact
ln case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
ln case of ingestion
not relevant
Physician's information / possible symptoms
The following symptoms may occur:
Unconsciousness
Anaesthetic state
Headache
Confusion
Dizziness
5. Firefighting measures
Suitable extinguishing media
Product does not burn, fire-extinguishing activities according to surrounding.
Special hazards arising from the substance or mixture
Exposure to fire may cause containers to rupture / explode.
Fire gas of organic material has to be classed invariably as respiratory poison.
ln the event of fire the following can be released:
Hydrogen fluoride (HF)
lgnitable gas-air-mixtures can be formed under special conditions.
Fluorine phosgene
Special protective equipment for fire-fighters
Use breathing apparatus with independent air supply.
Page 2/6
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 25.01.2011
Revision 19.01.2011
R-134a (1,1,1,2,-Tetrafluorethan) type test leak (n.
r.)
Do not inhale explosion and/or combustion gases.
Additional information
Heat action leads to pressure increase - risk of aerosol can bursting
Remove the endangered containers or spray them with cold water
6. Accidentai release measures
Persona! precautions
Ensure adequate ventilation.
Gas/vapours are heavier than air. They may Accumulate in confined spaces, in particular at or below ground.
Keep people away and stay on the upwind side.
Avoid skin contact with running out liquid (risk of frostbites! ).
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up
Allow to vaporise.
Take up with absorbent material.
7. Handling and storage
Advice on safe handling
Do not spray into a naked flame or any incandescent material.
Gare for thoroughly room ventilation, if necessary use in well ventilated area with-10-cal exhaust ventilation at workplace.-
Use only in well-ventilated areas.
Advice on protection against tire and explosion
Product is not inflammable
Further information on storage conditions
Protect from direct solar radiation.
Store container at cool and aired place.
Protect from heat/overheating.
Avoid heating to over 50 °C.
\..__...l-------------------------------------------------
8. Exposure controls/personal protection
Additional advice on system design
For good space ventilation provide, if necessary exhaust on the job.
lngredients with occupational exposure limits to be monitored
CAS No Name Code [mg/m3] [ppm] Remark
811-97-2 1,1,1,2-Tetrafluoroethane (HFC 134a) 8 hours 4240 1000 EH40/2005
Respiratory protection
Environment-independent breathing apparatus.
If ventilation insufficient, wear respiratory protection.
Hand protection
Low-temperature-resistant gloves
Glove material specification [make/type, thickness, permeation time/life, wetting resistance]: butyl rubber, 0,7mm;
480min; 60 min.
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant
standard EN374.
The selection of a suitable glove depends and from manufacturer to manufacturer different not only on the material, but
also on further quality criteria.
Page 3/6
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 25.01.2011
Revision 19.01.2011 '-.../
R-134a (1,1,1,2,-Tetrafluorethan) type test leak (n.
r.)
The exact breakthrough time of the glove material is to be inquired from the protèction glove manufacturer and must be
strictly adhered to.
Eye protection
safety goggles, in case of increased risk add protective face shield
Skin protection
Protective clothing
General protective measures
Avoid contact with eyes and skin
Do not inhale gases/vapours/aerosols.
Hygiene measures
Do not smoke when working.
Remove soaked clothing immediately.
Work in rooms with good ventilation.
9. Physical and chemical properties
Form Colour Odour
compressed liquified gas colourless ethereal
Important health, safety and environmental information
Value Temperature at Method Remark
boiling point ca. -26 °C
Flash point no
Lower explosion limit not applicable
Vapour pressure 5700 hPa 20 ·c
Density 1,21 g/cm3 25 °c as liquid
Solubility in water 1500 mg/1 25 °c 1013hPa
1 O. Stability and reactivity
Conditions to avoid
strong heating
Materials to avoid
Reactions with alkali metals.
Reactions with earth alkali metals.
Hazardous decomposition products
With regard to possible decomposition products refer to Section 5.
Page 4/6
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 25.01.2011
Revision 19.01.2011
R-134a (1,1,1,2,-Tetrafluorethan) type test leak (n.
r.)
11. Toxicological information
Experiences made from practice
Gases have a suffocating effect.
The inhalation of thermal decomposition products in form of vapeurs, mist or smoke may be damaging to the health.
Additional information
Other hazardous properties may not be excluded.
The…
